Recent advances in palladium-catalysed asymmetric 1,4–additions of arylboronic acids to conjugated enones and chromones

The transition metal (palladium)-catalysed asymmetric 1,4-addition of arylboronic acids to conjugated enones belong to the most important and emerging strategies for the construction of C–C bonds in an asymmetric fashion. This review covers known catalytic systems used for this transformation. For c...

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Autores principales: Bartáček, Jan, Svoboda, Jan, Kocúrik, Martin, Pochobradský, Jaroslav, Čegan, Alexander, Sedlák, Miloš, Váňa, Jiří
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2021
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8144908/
https://www.ncbi.nlm.nih.gov/pubmed/34093877
http://dx.doi.org/10.3762/bjoc.17.84
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author Bartáček, Jan
Svoboda, Jan
Kocúrik, Martin
Pochobradský, Jaroslav
Čegan, Alexander
Sedlák, Miloš
Váňa, Jiří
author_facet Bartáček, Jan
Svoboda, Jan
Kocúrik, Martin
Pochobradský, Jaroslav
Čegan, Alexander
Sedlák, Miloš
Váňa, Jiří
author_sort Bartáček, Jan
collection PubMed
description The transition metal (palladium)-catalysed asymmetric 1,4-addition of arylboronic acids to conjugated enones belong to the most important and emerging strategies for the construction of C–C bonds in an asymmetric fashion. This review covers known catalytic systems used for this transformation. For clarity, we are using the type of ligand as a sorting criterion. Finally, we attempted to create a flowchart facilitating the selection of a suitable ligand for a given combination of enone and arylboronic acid.
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spelling pubmed-81449082021-06-04 Recent advances in palladium-catalysed asymmetric 1,4–additions of arylboronic acids to conjugated enones and chromones Bartáček, Jan Svoboda, Jan Kocúrik, Martin Pochobradský, Jaroslav Čegan, Alexander Sedlák, Miloš Váňa, Jiří Beilstein J Org Chem Review The transition metal (palladium)-catalysed asymmetric 1,4-addition of arylboronic acids to conjugated enones belong to the most important and emerging strategies for the construction of C–C bonds in an asymmetric fashion. This review covers known catalytic systems used for this transformation. For clarity, we are using the type of ligand as a sorting criterion. Finally, we attempted to create a flowchart facilitating the selection of a suitable ligand for a given combination of enone and arylboronic acid. Beilstein-Institut 2021-05-10 /pmc/articles/PMC8144908/ /pubmed/34093877 http://dx.doi.org/10.3762/bjoc.17.84 Text en Copyright © 2021, Bartáček et al. https://creativecommons.org/licenses/by/4.0/https://www.beilstein-journals.org/bjoc/terms/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0 (https://creativecommons.org/licenses/by/4.0/) ). Please note that the reuse, redistribution and reproduction in particular requires that the author(s) and source are credited and that individual graphics may be subject to special legal provisions. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms/terms)
spellingShingle Review
Bartáček, Jan
Svoboda, Jan
Kocúrik, Martin
Pochobradský, Jaroslav
Čegan, Alexander
Sedlák, Miloš
Váňa, Jiří
Recent advances in palladium-catalysed asymmetric 1,4–additions of arylboronic acids to conjugated enones and chromones
title Recent advances in palladium-catalysed asymmetric 1,4–additions of arylboronic acids to conjugated enones and chromones
title_full Recent advances in palladium-catalysed asymmetric 1,4–additions of arylboronic acids to conjugated enones and chromones
title_fullStr Recent advances in palladium-catalysed asymmetric 1,4–additions of arylboronic acids to conjugated enones and chromones
title_full_unstemmed Recent advances in palladium-catalysed asymmetric 1,4–additions of arylboronic acids to conjugated enones and chromones
title_short Recent advances in palladium-catalysed asymmetric 1,4–additions of arylboronic acids to conjugated enones and chromones
title_sort recent advances in palladium-catalysed asymmetric 1,4–additions of arylboronic acids to conjugated enones and chromones
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8144908/
https://www.ncbi.nlm.nih.gov/pubmed/34093877
http://dx.doi.org/10.3762/bjoc.17.84
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