CsAlB(3)O(6)F: a beryllium-free deep-ultraviolet nonlinear optical material with enhanced thermal stability

The design of new beryllium-free deep-ultraviolet nonlinear optical materials is important but challenging. Here, we describe a new strategy to search for such materials based on rational selection of fundamental structural units. By combining asymmetric AlO(3)F tetrahedra and π-conjugated B(3)O(6)...

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Detalles Bibliográficos
Autores principales: Liu, Hongkun, Wang, Ying, Zhang, Bingbing, Yang, Zhihua, Pan, Shilie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8145444/
https://www.ncbi.nlm.nih.gov/pubmed/34123042
http://dx.doi.org/10.1039/c9sc04862f
Descripción
Sumario:The design of new beryllium-free deep-ultraviolet nonlinear optical materials is important but challenging. Here, we describe a new strategy to search for such materials based on rational selection of fundamental structural units. By combining asymmetric AlO(3)F tetrahedra and π-conjugated B(3)O(6) rings, a new aluminum borate fluoride, CsAlB(3)O(6)F was obtained. It exhibits excellent linear and nonlinear optical properties including a high optical transmittance with a cut-off edge shorter than 190 nm, large second harmonic generation intensities (2.0× KH(2)PO(4), KDP), and suitable birefringence for phase-matching under 200 nm. It also has good thermal stability and can be synthesized easily in an open system.

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