Base induced isomerisation of a phosphaethynolato-borane: mechanistic insights into boryl migration and decarbonylation to afford a triplet phosphinidene

We report on the (tert-butyl)isocyanide-catalysed isomersation of a phosphaethynolato-borane, [B]OCP ([B] = N,N′-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaboryl), to its linkage isomer, a phosphaketenyl-borane, [B]PCO. Mechanistic insight into this unusual isomerisation was gained through...

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Detalles Bibliográficos
Autores principales: Wilson, Daniel W. N., Franco, Mauricio P., Myers, William K., McGrady, John E., Goicoechea, Jose M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8145529/
https://www.ncbi.nlm.nih.gov/pubmed/34123064
http://dx.doi.org/10.1039/c9sc05969e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8145529/
https://www.ncbi.nlm.nih.gov/pubmed/34123064
http://dx.doi.org/10.1039/c9sc05969e

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