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Synthesis, characterization and C–H amination reactivity of nickel iminyl complexes

Metalation of the deprotonated dipyrrin ((AdF)L)Li with NiCl(2)(py)(2) afforded the divalent Ni product ((AdF)L)NiCl(py)(2) (1) ((AdF)L: 1,9-di(1-adamantyl)-5-perfluorophenyldipyrrin; py: pyridine). To generate a reactive synthon on which to explore oxidative group transfer, we used potassium graphi...

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Detalles Bibliográficos
Autores principales:	Dong, Yuyang, Lukens, James T., Clarke, Ryan M., Zheng, Shao-Liang, Lancaster, Kyle M., Betley, Theodore A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8147896/ https://www.ncbi.nlm.nih.gov/pubmed/34123250 http://dx.doi.org/10.1039/c9sc04879k

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