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Serine is the molecular source of the NH(CH(2))(2) bridgehead moiety of the in vitro assembled [FeFe] hydrogenase H-cluster
The active site of [FeFe] hydrogenase, the H-cluster, consists of a canonical [4Fe–4S](H) subcluster linked to a unique binuclear [2Fe](H) subcluster containing three CO, two CN(−) and a bridging azadithiolate (adt, NH(CH(2)S(−))(2)) ligand. While it is known that all five diatomic ligands are deriv...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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The Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8148037/ https://www.ncbi.nlm.nih.gov/pubmed/34123248 http://dx.doi.org/10.1039/c9sc05900h |