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Hydrophosphination of boron–boron multiple bonds

Five compounds containing boron–boron multiple bonds are shown to undergo hydrophosphination reactions with diphenylphosphine in the absence of a catalyst. With diborenes, the products obtained are highly dependent on the substitution pattern at the boron atoms, with both 1,1- and 1,2-hydrophosphina...

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Detalles Bibliográficos
Autores principales: Stennett, Tom E., Jayaraman, Arumugam, Brückner, Tobias, Schneider, Lea, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8148080/
https://www.ncbi.nlm.nih.gov/pubmed/34123256
http://dx.doi.org/10.1039/c9sc05908c