The role of lattice vibration in the terahertz region for proton conduction in 2D metal–organic frameworks

We studied the relationship between proton conductivity and the terahertz-regime vibrations of two-dimensional MOFs. The results of spectroscopy studies clarified the essential role played by the collective motions in the terahertz region in 2D layers for efficient H(+) conduction. Ab initio calcula...

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Detalles Bibliográficos
Autores principales: Itakura, Tomoya, Matsui, Hiroshi, Tada, Tomofumi, Kitagawa, Susumu, Demessence, Aude, Horike, Satoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8148082/
https://www.ncbi.nlm.nih.gov/pubmed/34084384
http://dx.doi.org/10.1039/c9sc05757a
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author Itakura, Tomoya
Matsui, Hiroshi
Tada, Tomofumi
Kitagawa, Susumu
Demessence, Aude
Horike, Satoshi
author_facet Itakura, Tomoya
Matsui, Hiroshi
Tada, Tomofumi
Kitagawa, Susumu
Demessence, Aude
Horike, Satoshi
author_sort Itakura, Tomoya
collection PubMed
description We studied the relationship between proton conductivity and the terahertz-regime vibrations of two-dimensional MOFs. The results of spectroscopy studies clarified the essential role played by the collective motions in the terahertz region in 2D layers for efficient H(+) conduction. Ab initio calculations suggested the collective motion to be predominantly determined by the valence electronic structure, depending on the identity of the metal ion.
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spelling pubmed-81480822021-06-02 The role of lattice vibration in the terahertz region for proton conduction in 2D metal–organic frameworks Itakura, Tomoya Matsui, Hiroshi Tada, Tomofumi Kitagawa, Susumu Demessence, Aude Horike, Satoshi Chem Sci Chemistry We studied the relationship between proton conductivity and the terahertz-regime vibrations of two-dimensional MOFs. The results of spectroscopy studies clarified the essential role played by the collective motions in the terahertz region in 2D layers for efficient H(+) conduction. Ab initio calculations suggested the collective motion to be predominantly determined by the valence electronic structure, depending on the identity of the metal ion. The Royal Society of Chemistry 2019-12-16 /pmc/articles/PMC8148082/ /pubmed/34084384 http://dx.doi.org/10.1039/c9sc05757a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Itakura, Tomoya
Matsui, Hiroshi
Tada, Tomofumi
Kitagawa, Susumu
Demessence, Aude
Horike, Satoshi
The role of lattice vibration in the terahertz region for proton conduction in 2D metal–organic frameworks
title The role of lattice vibration in the terahertz region for proton conduction in 2D metal–organic frameworks
title_full The role of lattice vibration in the terahertz region for proton conduction in 2D metal–organic frameworks
title_fullStr The role of lattice vibration in the terahertz region for proton conduction in 2D metal–organic frameworks
title_full_unstemmed The role of lattice vibration in the terahertz region for proton conduction in 2D metal–organic frameworks
title_short The role of lattice vibration in the terahertz region for proton conduction in 2D metal–organic frameworks
title_sort role of lattice vibration in the terahertz region for proton conduction in 2d metal–organic frameworks
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8148082/
https://www.ncbi.nlm.nih.gov/pubmed/34084384
http://dx.doi.org/10.1039/c9sc05757a
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