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Understanding disorder and linker deficiency in porphyrinic zirconium-based metal–organic frameworks by resolving the Zr(8)O(6) cluster conundrum in PCN-221
Porphyrin-based metal–organic frameworks (MOFs), exemplified by MOF-525, PCN-221, and PCN-224, are promising systems for catalysis, optoelectronics, and solar energy conversion. However, subtle differences between synthetic protocols for these three MOFs give rise to vast discrepancies in purported...
Autores principales: | , , , , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8149457/ https://www.ncbi.nlm.nih.gov/pubmed/34035286 http://dx.doi.org/10.1038/s41467-021-23348-w |