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Understanding disorder and linker deficiency in porphyrinic zirconium-based metal–organic frameworks by resolving the Zr(8)O(6) cluster conundrum in PCN-221

Porphyrin-based metal–organic frameworks (MOFs), exemplified by MOF-525, PCN-221, and PCN-224, are promising systems for catalysis, optoelectronics, and solar energy conversion. However, subtle differences between synthetic protocols for these three MOFs give rise to vast discrepancies in purported...

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Detalles Bibliográficos
Autores principales:	Koschnick, Charlotte, Stäglich, Robert, Scholz, Tanja, Terban, Maxwell W., von Mankowski, Alberto, Savasci, Gökcen, Binder, Florian, Schökel, Alexander, Etter, Martin, Nuss, Jürgen, Siegel, Renée, Germann, Luzia S., Ochsenfeld, Christian, Dinnebier, Robert E., Senker, Jürgen, Lotsch, Bettina V.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2021
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8149457/ https://www.ncbi.nlm.nih.gov/pubmed/34035286 http://dx.doi.org/10.1038/s41467-021-23348-w

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