Type 3 porous liquids based on non-ionic liquid phases – a broad and tailorable platform of selective, fluid gas sorbents

We describe a series of Type 3 porous liquids, denoted “T3PLs”, based on a wide range of microporous solids including MOFs, zeolites and a porous organic polymer (PAF-1). These solids are dispersed in various non-ionic liquid phases (including silicone oils, triglyceride oils, and polyethylene glyco...

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Autores principales: Cahir, John, Tsang, Min Ying, Lai, Beibei, Hughes, David, Alam, M. Ashraf, Jacquemin, Johan, Rooney, David, James, Stuart L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8150117/
https://www.ncbi.nlm.nih.gov/pubmed/34123297
http://dx.doi.org/10.1039/c9sc05770f
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author Cahir, John
Tsang, Min Ying
Lai, Beibei
Hughes, David
Alam, M. Ashraf
Jacquemin, Johan
Rooney, David
James, Stuart L.
author_facet Cahir, John
Tsang, Min Ying
Lai, Beibei
Hughes, David
Alam, M. Ashraf
Jacquemin, Johan
Rooney, David
James, Stuart L.
author_sort Cahir, John
collection PubMed
description We describe a series of Type 3 porous liquids, denoted “T3PLs”, based on a wide range of microporous solids including MOFs, zeolites and a porous organic polymer (PAF-1). These solids are dispersed in various non-ionic liquid phases (including silicone oils, triglyceride oils, and polyethylene glycols) which have a range of structures and properties, and that are in many cases sterically excluded from the pores of the solids. Several stable dispersions with high gas uptakes are obtained. We show how these dispersions can be tailored toward important gas separation processes (CO(2)/CH(4), C(2)H(4)/C(2)H(6)) and applications that require biocompatibility.
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spelling pubmed-81501172021-06-11 Type 3 porous liquids based on non-ionic liquid phases – a broad and tailorable platform of selective, fluid gas sorbents Cahir, John Tsang, Min Ying Lai, Beibei Hughes, David Alam, M. Ashraf Jacquemin, Johan Rooney, David James, Stuart L. Chem Sci Chemistry We describe a series of Type 3 porous liquids, denoted “T3PLs”, based on a wide range of microporous solids including MOFs, zeolites and a porous organic polymer (PAF-1). These solids are dispersed in various non-ionic liquid phases (including silicone oils, triglyceride oils, and polyethylene glycols) which have a range of structures and properties, and that are in many cases sterically excluded from the pores of the solids. Several stable dispersions with high gas uptakes are obtained. We show how these dispersions can be tailored toward important gas separation processes (CO(2)/CH(4), C(2)H(4)/C(2)H(6)) and applications that require biocompatibility. The Royal Society of Chemistry 2020-01-09 /pmc/articles/PMC8150117/ /pubmed/34123297 http://dx.doi.org/10.1039/c9sc05770f Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Cahir, John
Tsang, Min Ying
Lai, Beibei
Hughes, David
Alam, M. Ashraf
Jacquemin, Johan
Rooney, David
James, Stuart L.
Type 3 porous liquids based on non-ionic liquid phases – a broad and tailorable platform of selective, fluid gas sorbents
title Type 3 porous liquids based on non-ionic liquid phases – a broad and tailorable platform of selective, fluid gas sorbents
title_full Type 3 porous liquids based on non-ionic liquid phases – a broad and tailorable platform of selective, fluid gas sorbents
title_fullStr Type 3 porous liquids based on non-ionic liquid phases – a broad and tailorable platform of selective, fluid gas sorbents
title_full_unstemmed Type 3 porous liquids based on non-ionic liquid phases – a broad and tailorable platform of selective, fluid gas sorbents
title_short Type 3 porous liquids based on non-ionic liquid phases – a broad and tailorable platform of selective, fluid gas sorbents
title_sort type 3 porous liquids based on non-ionic liquid phases – a broad and tailorable platform of selective, fluid gas sorbents
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8150117/
https://www.ncbi.nlm.nih.gov/pubmed/34123297
http://dx.doi.org/10.1039/c9sc05770f
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