Strategies for remote enantiocontrol in chiral gold(iii) complexes applied to catalytic enantioselective γ,δ-Diels–Alder reactions

The use of chiral square planar gold(iii) complexes to access enantioenriched products has rarely been applied in asymmetric catalysis. In this context, we report a mechanistic and synthetic investigation into the use of N-heterocyclic (NHC) gold(iii) complexes in γ,δ-Diels–Alder reactions of 2,4-di...

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Detalles Bibliográficos
Autores principales: Reid, Jolene P., Hu, Mingyou, Ito, Susumu, Huang, Banruo, Hong, Cynthia M., Xiang, Hengye, Sigman, Matthew S., Toste, F. Dean
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8152632/
https://www.ncbi.nlm.nih.gov/pubmed/34094110
http://dx.doi.org/10.1039/d0sc00497a

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