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Biosynthetic access to the rare antiarose sugar via an unusual reductase-epimerase

Rubrolones, isatropolones, and rubterolones are recently isolated glycosylated tropolonids with notable biological activity. They share similar aglycone skeletons but differ in their sugar moieties, and rubterolones in particular have a rare deoxysugar antiarose of unknown biosynthetic provenance. D...

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Detalles Bibliográficos
Autores principales: Yan, Yijun, Yang, Jing, Wang, Li, Xu, Dongdong, Yu, Zhiyin, Guo, Xiaowei, Horsman, Geoff P., Lin, Shuangjun, Tao, Meifeng, Huang, Sheng-Xiong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8152690/
https://www.ncbi.nlm.nih.gov/pubmed/34122866
http://dx.doi.org/10.1039/c9sc05766h