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FLP-type nitrile activation and cyclic ether ring-opening by halo-borane nonagermanide-cluster Lewis acid–base pairs
Even though homoatomic nine-atom germanium clusters are known for two decades, their chemical properties are still rarely investigated. We now discovered that Zintl ion main group-element clusters possess a reactive lone pair of electrons, and we show a new pathway to bind ligands with functional gr...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8153081/ https://www.ncbi.nlm.nih.gov/pubmed/34123324 http://dx.doi.org/10.1039/d1sc00811k |