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Coal Fly Ash Decorated with Graphene Oxide–Tungsten Oxide Nanocomposite for Rapid Removal of Pb(2+) Ions and Reuse of Spent Adsorbent for Photocatalytic Degradation of Acetaminophen
[Image: see text] Coal fly ash was decorated with a graphene oxide–tungsten oxide nanorods nanocomposite (CFA/GO/WO(3)NRs nanocomposite) via a hydrothermal method and applied for the remediation of lead (Pb(2+) ions). The Pb(2+) ion-loaded spent adsorbent (CFA/GO/WO(3)NRs + Pb(2+) nanocomposite) was...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8153921/ https://www.ncbi.nlm.nih.gov/pubmed/34056271 http://dx.doi.org/10.1021/acsomega.0c04194 |
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author | Umejuru, Emmanuel Christopher Prabakaran, Eswaran Pillay, Kriveshini |
author_facet | Umejuru, Emmanuel Christopher Prabakaran, Eswaran Pillay, Kriveshini |
author_sort | Umejuru, Emmanuel Christopher |
collection | PubMed |
description | [Image: see text] Coal fly ash was decorated with a graphene oxide–tungsten oxide nanorods nanocomposite (CFA/GO/WO(3)NRs nanocomposite) via a hydrothermal method and applied for the remediation of lead (Pb(2+) ions). The Pb(2+) ion-loaded spent adsorbent (CFA/GO/WO(3)NRs + Pb(2+) nanocomposite) was reused for the photodegradation of acetaminophen. CFA/GO/WO(3)NRs + Pb(2+) nanocomposite displayed rapid removal of Pb(2+) ions. Pseudo-second-order kinetics and the Langmuir isotherm model described the adsorption data. The adsorption capacity of the CFA/GO/WO(3)NRs nanocomposite was 41.51 mg/g for the removal of Pb(2+) ions. Additionally, the Pb(2+) ion-loaded spent adsorbent significantly influenced the degradation of acetaminophen by photocatalysis where 93% degradation was observed. It is worthy to note the reuse application of Pb(2+) ion-loaded spent adsorbent as a photocatalyst, which will significantly reduce the secondary waste obtained from conventional adsorption methods. |
format | Online Article Text |
id | pubmed-8153921 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-81539212021-05-27 Coal Fly Ash Decorated with Graphene Oxide–Tungsten Oxide Nanocomposite for Rapid Removal of Pb(2+) Ions and Reuse of Spent Adsorbent for Photocatalytic Degradation of Acetaminophen Umejuru, Emmanuel Christopher Prabakaran, Eswaran Pillay, Kriveshini ACS Omega [Image: see text] Coal fly ash was decorated with a graphene oxide–tungsten oxide nanorods nanocomposite (CFA/GO/WO(3)NRs nanocomposite) via a hydrothermal method and applied for the remediation of lead (Pb(2+) ions). The Pb(2+) ion-loaded spent adsorbent (CFA/GO/WO(3)NRs + Pb(2+) nanocomposite) was reused for the photodegradation of acetaminophen. CFA/GO/WO(3)NRs + Pb(2+) nanocomposite displayed rapid removal of Pb(2+) ions. Pseudo-second-order kinetics and the Langmuir isotherm model described the adsorption data. The adsorption capacity of the CFA/GO/WO(3)NRs nanocomposite was 41.51 mg/g for the removal of Pb(2+) ions. Additionally, the Pb(2+) ion-loaded spent adsorbent significantly influenced the degradation of acetaminophen by photocatalysis where 93% degradation was observed. It is worthy to note the reuse application of Pb(2+) ion-loaded spent adsorbent as a photocatalyst, which will significantly reduce the secondary waste obtained from conventional adsorption methods. American Chemical Society 2021-04-22 /pmc/articles/PMC8153921/ /pubmed/34056271 http://dx.doi.org/10.1021/acsomega.0c04194 Text en © 2021 The Authors. Published by American Chemical Society Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Umejuru, Emmanuel Christopher Prabakaran, Eswaran Pillay, Kriveshini Coal Fly Ash Decorated with Graphene Oxide–Tungsten Oxide Nanocomposite for Rapid Removal of Pb(2+) Ions and Reuse of Spent Adsorbent for Photocatalytic Degradation of Acetaminophen |
title | Coal Fly Ash Decorated with Graphene Oxide–Tungsten
Oxide Nanocomposite for Rapid Removal of Pb(2+) Ions and
Reuse of Spent Adsorbent for Photocatalytic Degradation of Acetaminophen |
title_full | Coal Fly Ash Decorated with Graphene Oxide–Tungsten
Oxide Nanocomposite for Rapid Removal of Pb(2+) Ions and
Reuse of Spent Adsorbent for Photocatalytic Degradation of Acetaminophen |
title_fullStr | Coal Fly Ash Decorated with Graphene Oxide–Tungsten
Oxide Nanocomposite for Rapid Removal of Pb(2+) Ions and
Reuse of Spent Adsorbent for Photocatalytic Degradation of Acetaminophen |
title_full_unstemmed | Coal Fly Ash Decorated with Graphene Oxide–Tungsten
Oxide Nanocomposite for Rapid Removal of Pb(2+) Ions and
Reuse of Spent Adsorbent for Photocatalytic Degradation of Acetaminophen |
title_short | Coal Fly Ash Decorated with Graphene Oxide–Tungsten
Oxide Nanocomposite for Rapid Removal of Pb(2+) Ions and
Reuse of Spent Adsorbent for Photocatalytic Degradation of Acetaminophen |
title_sort | coal fly ash decorated with graphene oxide–tungsten
oxide nanocomposite for rapid removal of pb(2+) ions and
reuse of spent adsorbent for photocatalytic degradation of acetaminophen |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8153921/ https://www.ncbi.nlm.nih.gov/pubmed/34056271 http://dx.doi.org/10.1021/acsomega.0c04194 |
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