Cargando…

Substrate-Controlled Cu(OAc)(2)-Catalyzed Stereoselective Semi-Reduction of Alkynes with MeOH as the Hydrogen Source

[Image: see text] A substrate-controlled stereoselective semi-reduction of alkynes with MeOH as the hydrogen source has been developed, and readily available Cu(OAc)(2) (copper acetate) is utilized as an optimal catalyst. The detailed investigation of the mechanism revealed distinct catalytic proces...

Descripción completa

Detalles Bibliográficos
Autores principales:	Huang, Jiuzhong, Li, Xiaoning, Wen, Huiling, Ouyang, Lu, Luo, Nianhua, Liao, Jianhua, Luo, Renshi
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8154033/ https://www.ncbi.nlm.nih.gov/pubmed/34056327 http://dx.doi.org/10.1021/acsomega.1c01083

Ejemplares similares

Crystal Structure and Chemical Bonds in [Cu(II)(2)(Tolf)(4)(MeOH)(2)]∙2MeOH
por: Majerz, Irena, et al.
Publicado: (2023)

Chemical Adsorption Strategy for DMC-MeOH Mixture Separation †
por: Zhang, Fucan, et al.
Publicado: (2021)

Study of the Interactions between MeOH and Daidzein at the Molecular Level
por: Zhao, Hailiang, et al.
Publicado: (2021)

HCOOH disproportionation to MeOH promoted by molybdenum PNP complexes
por: Alberico, Elisabetta, et al.
Publicado: (2021)

Correction: HCOOH disproportionation to MeOH promoted by molybdenum PNP complexes
por: Alberico, Elisabetta, et al.
Publicado: (2021)

Molecular interaction between MeOH and genistein during soy extraction
por: Zhao, Hailiang, et al.
Publicado: (2019)

On the Coordination Chemistry of the lanthanum(III) Nitrate Salt in EAN/MeOH Mixtures
por: Migliorati, Valentina, et al.
Publicado: (2021)

Stereoselective cobalt-catalyzed halofluoroalkylation of alkynes
por: Wu, Guojiao, et al.
Publicado: (2018)

Silver‐Catalyzed Stereoselective Aminosulfonylation of Alkynes
por: Ning, Yongquan, et al.
Publicado: (2017)

Cyclometalated iridium complexes-catalyzed acceptorless dehydrogenative coupling reaction: construction of quinoline derivatives and evaluation of their antimicrobial activities
por: Shui, Hongling, et al.
Publicado: (2022)

Synthesis of MeOH and DME From CO(2) Hydrogenation Over Commercial and Modified Catalysts
por: Santiago, Rafaelle G., et al.
Publicado: (2022)

Reduction of Substituted Benzo-Fused Cyclic Sulfonamides with Mg-MeOH: An Experimental and Computational Study
por: Khalifa, Aisha, et al.
Publicado: (2022)

Stereoselective Gold(I)-Catalyzed Intermolecular Hydroalkoxlation of Alkynes
por: Veenboer, Richard M. P., et al.
Publicado: (2015)

Cyclometalated Iridium Complex-Catalyzed N-Alkylation of Amines with Alcohols via Borrowing Hydrogen in Aqueous Media
por: Luo, NianHua, et al.
Publicado: (2020)

4-AP-3-MeOH Promotes Structural and Functional Spontaneous Recovery in the Acute Sciatic Nerve Stretch Injury
por: Chen, Yan, et al.
Publicado: (2020)

Lycopus maackianus Makino MeOH Extract Exhibits Antioxidant and Anti-Neuroinflammatory Effects in Neuronal Cells and Zebrafish Model
por: Lee, Hwan, et al.
Publicado: (2022)

Biochemical Methanol Gas Sensor (MeOH Bio-Sniffer) for Non-Invasive Assessment of Intestinal Flora from Breath Methanol
por: Toma, Koji, et al.
Publicado: (2021)

Highly Efficient Gold(I)-Catalyzed Regio- and Stereoselective Hydrocarboxylation of Internal Alkynes
por: Dupuy, Stéphanie, et al.
Publicado: (2015)

Stereoselective Synthesis of Tertiary Allylic Amines by Titanium‐Catalyzed Hydroaminoalkylation of Alkynes with Tertiary Amines
por: Kaper, Tobias, et al.
Publicado: (2022)

Stereoselective Semi‐Hydrogenations of Alkynes by First‐Row (3d) Transition Metal Catalysts
por: Gregori, Bernhard J., et al.
Publicado: (2022)

Stereoselectivity control in Rh-catalyzed β-OH elimination for chiral allene formation
por: Wang, Jie, et al.
Publicado: (2023)

Cationic-palladium catalyzed regio- and stereoselective syn-1,2-dicarbofunctionalization of unsymmetrical internal alkynes
por: Dutta, Shubham, et al.
Publicado: (2022)

Polyhedral Cu(2)O to Cu pseudomorphic conversion for stereoselective alkyne semihydrogenation
por: Rej, Sourav, et al.
Publicado: (2018)

Stereoselective synthesis of pentasubstituted 1,3-dienes via Ni-catalyzed reductive coupling of unsymmetrical internal alkynes
por: Zhou, Zhijun, et al.
Publicado: (2020)

Iodine-promoted stereoselective amidosulfenylation of electron-deficient alkynes
por: Xiao, Fuhong, et al.
Publicado: (2018)

One-pot reductive amination of carbonyl compounds and nitro compounds via Ir-catalyzed transfer hydrogenation
por: Luo, Renshi, et al.
Publicado: (2023)

Pd(OAc)(2)-catalyzed asymmetric hydrogenation of sterically hindered N-tosylimines
por: Chen, Jianzhong, et al.
Publicado: (2018)

Iridium Complex-Catalyzed Transfer Hydrogenation of N-Heteroarenes and Tentative Asymmetric Synthesis
por: Ouyang, Lu, et al.
Publicado: (2021)

Single and Double-Stranded 1D-Coordination Polymers with 4′-(4-Alkyloxyphenyl)-3,2′:6′,3″-terpyridines and {Cu(2)(μ-OAc)(4)} or {Cu(4)(μ(3)-OH)(2)(μ-OAc)(2)(μ(3)-OAc)(2)(AcO-κO)(2)} Motifs
por: Rocco, Dalila, et al.
Publicado: (2020)

Copper-Catalyzed Diboron-Mediated cis-Semi-Hydrogenation of Alkynes under Facile Conditions
por: Zeng, Yuxi, et al.
Publicado: (2022)

Comparison of Magnetic Deflection among Neutral Sodium-Doped Clusters: Na(H(2)O)(n), Na(NH(3))(n), Na(MeOH)(n), and Na(DME)(n)
por: Barnes, Jonathan V., et al.
Publicado: (2023)

Reactions of [60]fullerene with alkynes promoted by OH(−)
por: Chang, Wei-Wei, et al.
Publicado: (2022)

Volumetric Properties of the {x(1)[C(4)mim][MeSO(4)] + (1 − x(1))MeOH} System at Temperatures from (283.15 to 333.15) K and Pressures from (0.1 to 35) MPa
por: Matkowska, Dobrochna, et al.
Publicado: (2013)

Electronic and solvent effects on kinetics of S(N)Ar substitution reactions of substituted anilines with 2,6-bis(trifluoromethanesulfonyl)-4-nitroanisole in MeOH–Me(2)SO mixtures of varying composition: one reaction with two mechanistic pathways
por: El Guesmi, Nizar, et al.
Publicado: (2013)

Parts-Per-Million of Soluble Pd(0) Catalyze the Semi-Hydrogenation Reaction of Alkynes to Alkenes
por: Ballesteros-Soberanas, Jordi, et al.
Publicado: (2022)

Stereoselective Metabolism of Bupropion to OH-bupropion, Threohydrobupropion, Erythrohydrobupropion, and 4′-OH-bupropion in vitro
por: Sager, Jennifer E., et al.
Publicado: (2016)

Pd(OAc)(2)/Ph(3)P-catalyzed dimerization of isoprene and synthesis of monoterpenic heterocycles
por: Kellner, Dominik, et al.
Publicado: (2017)

Correction: Reactions of [60]fullerene with alkynes promoted by OH(−)
por: Chang, Wei-Wei, et al.
Publicado: (2022)

Structural Determinants of Alkyne Reactivity in Copper-Catalyzed Azide-Alkyne Cycloadditions
por: Zhang, Xiaoguang, et al.
Publicado: (2016)

Stereoselective Promiscuous Reactions Catalyzed by Lipases
por: Patti, Angela, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_ki0m8prc50q27cavkmbl4570e3