Expected and Unexpected Reactivities of Homoleptic LiNacNac and Heteroleptic NacNacMg(TMP) β-Diketiminates toward Various Small Unsaturated Organic Molecules

[Image: see text] Homoleptic LiNacNac forms simple donor–acceptor complexes with N,N′-dicyclohexylcarbodiimide (CyN=C=NCy), triphenylphosphine oxide (Ph(3)P=O), and benzophenone (Ph(2)CO). These crystallographically characterized compounds could be regarded as model intermediates en route to reducin...

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Detalles Bibliográficos
Autores principales: Gauld, Richard M., Lynch, Jennifer R., Kennedy, Alan R., Barker, Jim, Reid, Jacqueline, Mulvey, Robert E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8154426/
https://www.ncbi.nlm.nih.gov/pubmed/33830739
http://dx.doi.org/10.1021/acs.inorgchem.1c00549

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