Productive Alkyne Metathesis with “Canopy Catalysts” Mandates Pseudorotation

[Image: see text] Molybdenum alkylidyne complexes of the “canopy catalyst” series define new standards in the field of alkyne metathesis. The tripodal ligand framework lowers the symmetry of the metallacyclobutadiene complex formed by [2 + 2] cycloaddition with the substrate and imposes constraints...

Descripción completa

Detalles Bibliográficos
Autores principales: Haack, Alexander, Hillenbrand, Julius, Leutzsch, Markus, van Gastel, Maurice, Neese, Frank, Fürstner, Alois
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8154524/
https://www.ncbi.nlm.nih.gov/pubmed/33826335
http://dx.doi.org/10.1021/jacs.1c01404

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8154524/
https://www.ncbi.nlm.nih.gov/pubmed/33826335
http://dx.doi.org/10.1021/jacs.1c01404

Ejemplares similares