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Productive Alkyne Metathesis with “Canopy Catalysts” Mandates Pseudorotation
[Image: see text] Molybdenum alkylidyne complexes of the “canopy catalyst” series define new standards in the field of alkyne metathesis. The tripodal ligand framework lowers the symmetry of the metallacyclobutadiene complex formed by [2 + 2] cycloaddition with the substrate and imposes constraints...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8154524/ https://www.ncbi.nlm.nih.gov/pubmed/33826335 http://dx.doi.org/10.1021/jacs.1c01404 |