A Monomeric Aluminum Imide (Iminoalane) with Al–N Triple-Bonding: Bonding Analysis and Dispersion Energy Stabilization

[Image: see text] The reaction of :AlAr(iPr8) (Ar(iPr8) = C(6)H-2,6-(C(6)H(2)-2,4,6-(i)Pr(3))(2)-3,5-(i)Pr(2)) with Ar(Me6)N(3) (Ar(Me6) = C(6)H(3)-2,6-(C(6)H(2)-2,4,6-Me(3))(2)) in hexanes at ambient temperature gave the aluminum imide Ar(iPr8)AlNAr(Me6) (1). Its crystal structure displayed short A...

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Detalles Bibliográficos
Autores principales: Queen, Joshua D., Irvankoski, Sini, Fettinger, James C., Tuononen, Heikki M., Power, Philip P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8154528/
https://www.ncbi.nlm.nih.gov/pubmed/33882237
http://dx.doi.org/10.1021/jacs.1c02463

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