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A New Ligand Design Based on London Dispersion Empowers Chiral Bismuth–Rhodium Paddlewheel Catalysts

[Image: see text] Heterobimetallic bismuth–rhodium paddlewheel complexes with phenylglycine ligands carrying TIPS-groups at the meta-positions of the aromatic ring exhibit outstanding levels of selectivity in reactions of donor/acceptor and donor/donor carbenes; at the same time, the reaction rates...

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Detalles Bibliográficos
Autores principales:	Singha, Santanu, Buchsteiner, Michael, Bistoni, Giovanni, Goddard, Richard, Fürstner, Alois
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8154533/ https://www.ncbi.nlm.nih.gov/pubmed/33829767 http://dx.doi.org/10.1021/jacs.1c01972

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