Cargando…
A Series of Crystallographically Characterized Linear and Branched σ-Alkane Complexes of Rhodium: From Propane to 3-Methylpentane
[Image: see text] Using solid-state molecular organometallic (SMOM) techniques, in particular solid/gas single-crystal to single-crystal reactivity, a series of σ-alkane complexes of the general formula [Rh(Cy(2)PCH(2)CH(2)PCy(2))(η(n):η(m)-alkane)][BAr(F)(4)] have been prepared (alkane = propane, 2...
Autores principales: | Bukvic, Alexander J., Burnage, Arron L., Tizzard, Graham J., Martínez-Martínez, Antonio J., McKay, Alasdair I., Rees, Nicholas H., Tegner, Bengt E., Krämer, Tobias, Fish, Heather, Warren, Mark R., Coles, Simon J., Macgregor, Stuart A., Weller, Andrew S. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2021
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8154534/ https://www.ncbi.nlm.nih.gov/pubmed/33769815 http://dx.doi.org/10.1021/jacs.1c00738 |
Ejemplares similares
-
Room
Temperature Acceptorless Alkane Dehydrogenation
from Molecular σ-Alkane Complexes
por: McKay, Alasdair I., et al.
Publicado: (2019) -
Selectivity of Rh⋅⋅⋅H−C Binding in a σ‐Alkane Complex Controlled by the Secondary Microenvironment in the Solid State
por: Furfari, Samantha K., et al.
Publicado: (2021) -
A Structurally Characterized Cobalt(I) σ‐Alkane Complex
por: Boyd, Timothy M., et al.
Publicado: (2020) -
Inverse Isotope Effects in Single-Crystal to Single-Crystal
Reactivity and the Isolation of a Rhodium Cyclooctane σ-Alkane
Complex
por: Doyle, Laurence R., et al.
Publicado: (2022) -
Ortho-aryl substituted DPEphos ligands: rhodium complexes featuring C–H anagostic interactions and B–H agostic bonds
por: Race, James J., et al.
Publicado: (2021)