Synthesis of d-Galactose-Substituted Acylsilanes and Acylgermanes. Model Compounds for Visible Light Photoinitiators with Intriguing High Solubility

[Image: see text] A convenient synthetic method to obtain d-galactose-substituted acylsilanes and acylgermanes is described. These acyl group 14 compounds are easily accessible in good yields. Their structural properties were analyzed by a combination of NMR, single crystal X-ray crystallography, an...

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Detalles Bibliográficos
Autores principales: Schuh, Lukas, Müller, Philipp, Torvisco, Ana, Stueger, Harald, Wrodnigg, Tanja M., Haas, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8155559/
https://www.ncbi.nlm.nih.gov/pubmed/34054184
http://dx.doi.org/10.1021/acs.organomet.0c00753
Descripción
Sumario:[Image: see text] A convenient synthetic method to obtain d-galactose-substituted acylsilanes and acylgermanes is described. These acyl group 14 compounds are easily accessible in good yields. Their structural properties were analyzed by a combination of NMR, single crystal X-ray crystallography, and UV/vis spectroscopy. A d-galactose-substituted tetraacylgermane represents a new interesting visible light photoinitiator based on its absorption properties as well as its high solubility.

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