Synthesis of d-Galactose-Substituted Acylsilanes and Acylgermanes. Model Compounds for Visible Light Photoinitiators with Intriguing High Solubility

[Image: see text] A convenient synthetic method to obtain d-galactose-substituted acylsilanes and acylgermanes is described. These acyl group 14 compounds are easily accessible in good yields. Their structural properties were analyzed by a combination of NMR, single crystal X-ray crystallography, an...

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Autores principales: Schuh, Lukas, Müller, Philipp, Torvisco, Ana, Stueger, Harald, Wrodnigg, Tanja M., Haas, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8155559/
https://www.ncbi.nlm.nih.gov/pubmed/34054184
http://dx.doi.org/10.1021/acs.organomet.0c00753
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author Schuh, Lukas
Müller, Philipp
Torvisco, Ana
Stueger, Harald
Wrodnigg, Tanja M.
Haas, Michael
author_facet Schuh, Lukas
Müller, Philipp
Torvisco, Ana
Stueger, Harald
Wrodnigg, Tanja M.
Haas, Michael
author_sort Schuh, Lukas
collection PubMed
description [Image: see text] A convenient synthetic method to obtain d-galactose-substituted acylsilanes and acylgermanes is described. These acyl group 14 compounds are easily accessible in good yields. Their structural properties were analyzed by a combination of NMR, single crystal X-ray crystallography, and UV/vis spectroscopy. A d-galactose-substituted tetraacylgermane represents a new interesting visible light photoinitiator based on its absorption properties as well as its high solubility.
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spelling pubmed-81555592021-05-28 Synthesis of d-Galactose-Substituted Acylsilanes and Acylgermanes. Model Compounds for Visible Light Photoinitiators with Intriguing High Solubility Schuh, Lukas Müller, Philipp Torvisco, Ana Stueger, Harald Wrodnigg, Tanja M. Haas, Michael Organometallics [Image: see text] A convenient synthetic method to obtain d-galactose-substituted acylsilanes and acylgermanes is described. These acyl group 14 compounds are easily accessible in good yields. Their structural properties were analyzed by a combination of NMR, single crystal X-ray crystallography, and UV/vis spectroscopy. A d-galactose-substituted tetraacylgermane represents a new interesting visible light photoinitiator based on its absorption properties as well as its high solubility. American Chemical Society 2021-04-27 2021-05-10 /pmc/articles/PMC8155559/ /pubmed/34054184 http://dx.doi.org/10.1021/acs.organomet.0c00753 Text en © 2021 The Authors. Published by American Chemical Society Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Schuh, Lukas
Müller, Philipp
Torvisco, Ana
Stueger, Harald
Wrodnigg, Tanja M.
Haas, Michael
Synthesis of d-Galactose-Substituted Acylsilanes and Acylgermanes. Model Compounds for Visible Light Photoinitiators with Intriguing High Solubility
title Synthesis of d-Galactose-Substituted Acylsilanes and Acylgermanes. Model Compounds for Visible Light Photoinitiators with Intriguing High Solubility
title_full Synthesis of d-Galactose-Substituted Acylsilanes and Acylgermanes. Model Compounds for Visible Light Photoinitiators with Intriguing High Solubility
title_fullStr Synthesis of d-Galactose-Substituted Acylsilanes and Acylgermanes. Model Compounds for Visible Light Photoinitiators with Intriguing High Solubility
title_full_unstemmed Synthesis of d-Galactose-Substituted Acylsilanes and Acylgermanes. Model Compounds for Visible Light Photoinitiators with Intriguing High Solubility
title_short Synthesis of d-Galactose-Substituted Acylsilanes and Acylgermanes. Model Compounds for Visible Light Photoinitiators with Intriguing High Solubility
title_sort synthesis of d-galactose-substituted acylsilanes and acylgermanes. model compounds for visible light photoinitiators with intriguing high solubility
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8155559/
https://www.ncbi.nlm.nih.gov/pubmed/34054184
http://dx.doi.org/10.1021/acs.organomet.0c00753
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