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Enantioselective para-Claisen Rearrangement for the Synthesis of Illicium-Derived Prenylated Phenylpropanoids
[Image: see text] The development of the first enantioselective para-Claisen rearrangement has been achieved. Using a chiral aluminum Lewis acid, illicinole is rearranged to give (−)-illicinone A (er 87:13), which can then be converted into more complex Illicium-derived prenylated phenylpropanoids....
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8155563/ https://www.ncbi.nlm.nih.gov/pubmed/33856817 http://dx.doi.org/10.1021/acs.orglett.1c00620 |