Preparation of Neutral trans - cis [Ru(O(2)CR)(2)P(2)(NN)], Cationic [Ru(O(2)CR)P(2)(NN)](O(2)CR) and Pincer [Ru(O(2)CR)(CNN)P(2)] (P = PPh(3), P(2) = diphosphine) Carboxylate Complexes and their Application in the Catalytic Carbonyl Compounds Reduction

[Image: see text] The diacetate complexes trans-[Ru(κ(1)-OAc)(2)(PPh(3))(2)(NN)] (NN = ethylenediamine (en) (1), 2-(aminomethyl)pyridine (ampy) (2), 2-(aminomethyl)pyrimidine (ampyrim) (3)) have been isolated in 76–88% yield by reaction of [Ru(κ(2)-OAc)(2)(PPh(3))(2)] with the corresponding nitrogen...

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Detalles Bibliográficos
Autores principales: Baldino, Salvatore, Giboulot, Steven, Lovison, Denise, Nedden, Hans Günter, Pöthig, Alexander, Zanotti-Gerosa, Antonio, Zuccaccia, Daniele, Ballico, Maurizio, Baratta, Walter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8155570/
https://www.ncbi.nlm.nih.gov/pubmed/34054183
http://dx.doi.org/10.1021/acs.organomet.1c00059

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