Dehydrogenative C–H Phenochalcogenazination

[Image: see text] Heavy-atom-modified chalcogen-fused triarylamine organic materials are becoming increasingly important in the photochemical sciences. In this context, the general and direct dehydrogenative C–H phenochalcogenazination of phenols with the heavier chalcogens selenium and tellurium is...

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Autores principales: Cremer, Christopher, Eltester, M. Alexander, Bourakhouadar, Hicham, Atodiresei, Iuliana L., Patureau, Frederic W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8155573/
https://www.ncbi.nlm.nih.gov/pubmed/33848168
http://dx.doi.org/10.1021/acs.orglett.1c00573
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author Cremer, Christopher
Eltester, M. Alexander
Bourakhouadar, Hicham
Atodiresei, Iuliana L.
Patureau, Frederic W.
author_facet Cremer, Christopher
Eltester, M. Alexander
Bourakhouadar, Hicham
Atodiresei, Iuliana L.
Patureau, Frederic W.
author_sort Cremer, Christopher
collection PubMed
description [Image: see text] Heavy-atom-modified chalcogen-fused triarylamine organic materials are becoming increasingly important in the photochemical sciences. In this context, the general and direct dehydrogenative C–H phenochalcogenazination of phenols with the heavier chalcogens selenium and tellurium is herein described. The latter dehydrogenative C–N bond-forming processes operate under simple reaction conditions with highly sustainable O(2) serving as the terminal oxidant.
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spelling pubmed-81555732021-05-28 Dehydrogenative C–H Phenochalcogenazination Cremer, Christopher Eltester, M. Alexander Bourakhouadar, Hicham Atodiresei, Iuliana L. Patureau, Frederic W. Org Lett [Image: see text] Heavy-atom-modified chalcogen-fused triarylamine organic materials are becoming increasingly important in the photochemical sciences. In this context, the general and direct dehydrogenative C–H phenochalcogenazination of phenols with the heavier chalcogens selenium and tellurium is herein described. The latter dehydrogenative C–N bond-forming processes operate under simple reaction conditions with highly sustainable O(2) serving as the terminal oxidant. American Chemical Society 2021-04-13 2021-05-07 /pmc/articles/PMC8155573/ /pubmed/33848168 http://dx.doi.org/10.1021/acs.orglett.1c00573 Text en © 2021 The Authors. Published by American Chemical Society Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Cremer, Christopher
Eltester, M. Alexander
Bourakhouadar, Hicham
Atodiresei, Iuliana L.
Patureau, Frederic W.
Dehydrogenative C–H Phenochalcogenazination
title Dehydrogenative C–H Phenochalcogenazination
title_full Dehydrogenative C–H Phenochalcogenazination
title_fullStr Dehydrogenative C–H Phenochalcogenazination
title_full_unstemmed Dehydrogenative C–H Phenochalcogenazination
title_short Dehydrogenative C–H Phenochalcogenazination
title_sort dehydrogenative c–h phenochalcogenazination
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8155573/
https://www.ncbi.nlm.nih.gov/pubmed/33848168
http://dx.doi.org/10.1021/acs.orglett.1c00573
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AT eltestermalexander dehydrogenativechphenochalcogenazination
AT bourakhouadarhicham dehydrogenativechphenochalcogenazination
AT atodireseiiulianal dehydrogenativechphenochalcogenazination
AT patureaufredericw dehydrogenativechphenochalcogenazination

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