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Cross-dehydrogenative coupling enables enantioselective access to CF(3)-substituted all-carbon quaternary stereocenters

A cross-dehydrogenative coupling strategy for enantioselective access to acyclic CF(3)-substituted all-carbon quaternary stereocenters has been established. By using catalytic DDQ with MnO(2) as an inexpensive terminal oxidant, asymmetric cross coupling of racemic δ-CF(3)-substituted phenols with in...

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Detalles Bibliográficos
Autores principales:	Pan, Xiaoguang, Wang, Zehua, Kan, Linglong, Mao, Ying, Zhu, Yasheng, Liu, Lei
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157275/ https://www.ncbi.nlm.nih.gov/pubmed/34084405 http://dx.doi.org/10.1039/c9sc05894j

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