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Probing a variation of the inverse-trans-influence in americium and lanthanide tribromide tris(tricyclohexylphosphine oxide) complexes

The synthesis, characterization, and theoretical analysis of meridional americium tribromide tris(tricyclohexylphosphine oxide), mer-AmBr3(OPcy3)3, has been achieved and is compared with its early lanthanide (La to Nd) analogs. The data show that homo trans ligands display significantly shorter bond...

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Detalles Bibliográficos
Autores principales: Windorff, Cory J., Celis-Barros, Cristian, Sperling, Joseph M., McKinnon, Noah C., Albrecht-Schmitt, Thomas E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157511/
https://www.ncbi.nlm.nih.gov/pubmed/34084337
http://dx.doi.org/10.1039/c9sc05268b