Dearomatization of aryl sulfoxides: a switch between mono- and dual-difluoroalkylation

Herein we describe the dearomatization of aryl sulfoxides with difluoroenol silyl ether (DFESE) using a rearrangement/addition protocol. The selection of the sulfoxide activator determines whether one or two difluoroalkyl groups are incorporated into dearomatized products. Using TFAA can deliberatel...

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Detalles Bibliográficos
Autores principales: Huang, Xin, Zhang, Yage, Liang, Weijian, Zhang, Qifeng, Zhan, Yaling, Kong, Lichun, Peng, Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157523/
https://www.ncbi.nlm.nih.gov/pubmed/34122809
http://dx.doi.org/10.1039/d0sc00244e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157523/
https://www.ncbi.nlm.nih.gov/pubmed/34122809
http://dx.doi.org/10.1039/d0sc00244e

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