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C*-BODIPYs: Exploring a New Strategy to Transfer Chirality towards BODIPY Chiroptics(†)
C*-BODIPYs, that is, boron dipyrromethenes (BODIPYs) which have chiral carbons attached directly to the boron center, are introduced for the first time. These novel chiral BODIPYs mean a new strategy for the chiral perturbation of the inherently achiral BODIPY chromophore that is directed to enable...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157537/ https://www.ncbi.nlm.nih.gov/pubmed/34056640 http://dx.doi.org/10.3390/ecsoc-23-06610 |
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author | Jiménez, Josué Sánchez-Camacho, Juan Moreno, Florencio Agarrabeitia, Antonia R. Arbeloa, Teresa Cabreros, Trevor A. Muller, Gilles Bañuelos, Jorge Maroto, Beatriz L. de la Moya, Santiago |
author_facet | Jiménez, Josué Sánchez-Camacho, Juan Moreno, Florencio Agarrabeitia, Antonia R. Arbeloa, Teresa Cabreros, Trevor A. Muller, Gilles Bañuelos, Jorge Maroto, Beatriz L. de la Moya, Santiago |
author_sort | Jiménez, Josué |
collection | PubMed |
description | C*-BODIPYs, that is, boron dipyrromethenes (BODIPYs) which have chiral carbons attached directly to the boron center, are introduced for the first time. These novel chiral BODIPYs mean a new strategy for the chiral perturbation of the inherently achiral BODIPY chromophore that is directed to enable chiroptical properties. Their preparation is very simple and only implies the complexation of a dipyrrin with an enantiopure dialkylborane having boron bonded to chiral carbons. |
format | Online Article Text |
id | pubmed-8157537 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
record_format | MEDLINE/PubMed |
spelling | pubmed-81575372021-05-27 C*-BODIPYs: Exploring a New Strategy to Transfer Chirality towards BODIPY Chiroptics(†) Jiménez, Josué Sánchez-Camacho, Juan Moreno, Florencio Agarrabeitia, Antonia R. Arbeloa, Teresa Cabreros, Trevor A. Muller, Gilles Bañuelos, Jorge Maroto, Beatriz L. de la Moya, Santiago Proc West Mark Ed Assoc Conf Article C*-BODIPYs, that is, boron dipyrromethenes (BODIPYs) which have chiral carbons attached directly to the boron center, are introduced for the first time. These novel chiral BODIPYs mean a new strategy for the chiral perturbation of the inherently achiral BODIPY chromophore that is directed to enable chiroptical properties. Their preparation is very simple and only implies the complexation of a dipyrrin with an enantiopure dialkylborane having boron bonded to chiral carbons. 2020-01-20 2019-11-14 /pmc/articles/PMC8157537/ /pubmed/34056640 http://dx.doi.org/10.3390/ecsoc-23-06610 Text en https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) ). |
spellingShingle | Article Jiménez, Josué Sánchez-Camacho, Juan Moreno, Florencio Agarrabeitia, Antonia R. Arbeloa, Teresa Cabreros, Trevor A. Muller, Gilles Bañuelos, Jorge Maroto, Beatriz L. de la Moya, Santiago C*-BODIPYs: Exploring a New Strategy to Transfer Chirality towards BODIPY Chiroptics(†) |
title | C*-BODIPYs: Exploring a New Strategy to Transfer Chirality towards BODIPY Chiroptics(†) |
title_full | C*-BODIPYs: Exploring a New Strategy to Transfer Chirality towards BODIPY Chiroptics(†) |
title_fullStr | C*-BODIPYs: Exploring a New Strategy to Transfer Chirality towards BODIPY Chiroptics(†) |
title_full_unstemmed | C*-BODIPYs: Exploring a New Strategy to Transfer Chirality towards BODIPY Chiroptics(†) |
title_short | C*-BODIPYs: Exploring a New Strategy to Transfer Chirality towards BODIPY Chiroptics(†) |
title_sort | c*-bodipys: exploring a new strategy to transfer chirality towards bodipy chiroptics(†) |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157537/ https://www.ncbi.nlm.nih.gov/pubmed/34056640 http://dx.doi.org/10.3390/ecsoc-23-06610 |
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