A germaaluminocene

The reactions of dipotassium germacyclopentadienediide with two Group 13 dichlorides, Cp*BCl(2) and Cp*AlCl(2), yield two structurally different products. In the case of boron a borole complex of germanium(ii) is obtained. The aluminium halide gives an unprecedented neutral germaaluminocene. Both co...

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Detalles Bibliográficos
Autores principales: Albers, Lena, Tholen, Patrik, Schmidtmann, Marc, Müller, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157613/
https://www.ncbi.nlm.nih.gov/pubmed/34122799
http://dx.doi.org/10.1039/d0sc00401d
Descripción
Sumario:The reactions of dipotassium germacyclopentadienediide with two Group 13 dichlorides, Cp*BCl(2) and Cp*AlCl(2), yield two structurally different products. In the case of boron a borole complex of germanium(ii) is obtained. The aluminium halide gives an unprecedented neutral germaaluminocene. Both compounds were fully characterised by multinuclear NMR spectroscopy supported by DFT computations. The molecular structure of the germaaluminocene was determined by XRD.

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