A germaaluminocene

The reactions of dipotassium germacyclopentadienediide with two Group 13 dichlorides, Cp*BCl(2) and Cp*AlCl(2), yield two structurally different products. In the case of boron a borole complex of germanium(ii) is obtained. The aluminium halide gives an unprecedented neutral germaaluminocene. Both co...

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Detalles Bibliográficos
Autores principales: Albers, Lena, Tholen, Patrik, Schmidtmann, Marc, Müller, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157613/
https://www.ncbi.nlm.nih.gov/pubmed/34122799
http://dx.doi.org/10.1039/d0sc00401d
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author Albers, Lena
Tholen, Patrik
Schmidtmann, Marc
Müller, Thomas
author_facet Albers, Lena
Tholen, Patrik
Schmidtmann, Marc
Müller, Thomas
author_sort Albers, Lena
collection PubMed
description The reactions of dipotassium germacyclopentadienediide with two Group 13 dichlorides, Cp*BCl(2) and Cp*AlCl(2), yield two structurally different products. In the case of boron a borole complex of germanium(ii) is obtained. The aluminium halide gives an unprecedented neutral germaaluminocene. Both compounds were fully characterised by multinuclear NMR spectroscopy supported by DFT computations. The molecular structure of the germaaluminocene was determined by XRD.
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spelling pubmed-81576132021-06-11 A germaaluminocene Albers, Lena Tholen, Patrik Schmidtmann, Marc Müller, Thomas Chem Sci Chemistry The reactions of dipotassium germacyclopentadienediide with two Group 13 dichlorides, Cp*BCl(2) and Cp*AlCl(2), yield two structurally different products. In the case of boron a borole complex of germanium(ii) is obtained. The aluminium halide gives an unprecedented neutral germaaluminocene. Both compounds were fully characterised by multinuclear NMR spectroscopy supported by DFT computations. The molecular structure of the germaaluminocene was determined by XRD. The Royal Society of Chemistry 2020-02-10 /pmc/articles/PMC8157613/ /pubmed/34122799 http://dx.doi.org/10.1039/d0sc00401d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Albers, Lena
Tholen, Patrik
Schmidtmann, Marc
Müller, Thomas
A germaaluminocene
title A germaaluminocene
title_full A germaaluminocene
title_fullStr A germaaluminocene
title_full_unstemmed A germaaluminocene
title_short A germaaluminocene
title_sort germaaluminocene
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8157613/
https://www.ncbi.nlm.nih.gov/pubmed/34122799
http://dx.doi.org/10.1039/d0sc00401d
work_keys_str_mv AT alberslena agermaaluminocene
AT tholenpatrik agermaaluminocene
AT schmidtmannmarc agermaaluminocene
AT mullerthomas agermaaluminocene
AT alberslena germaaluminocene
AT tholenpatrik germaaluminocene
AT schmidtmannmarc germaaluminocene
AT mullerthomas germaaluminocene

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