Generation of a Hetero Spin Complex from Iron(II) Iodide with Redox Active Acenaphthene-1,2-Diimine

The reaction of the redox active 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dpp-BIAN) and iron(II) iodide in acetonitrile led to a new complex [(dpp-BIAN)Fe(II)I(2)] (1). Molecular structure of 1 was determined by the single crystal X-ray diffraction analysis. The spin state of the iron cati...

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Detalles Bibliográficos
Autores principales: Yambulatov, Dmitriy S., Nikolaevskii, Stanislav A., Kiskin, Mikhail A., Kholin, Kirill V., Khrizanforov, Mikhail N., Budnikova, Yulia G., Babeshkin, Konstantin A., Efimov, Nikolay N., Goloveshkin, Alexander S., Imshennik, Vladimir K., Maksimov, Yurii V., Kadilenko, Evgeny M., Gritsan, Nina P., Eremenko, Igor L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8158106/
https://www.ncbi.nlm.nih.gov/pubmed/34070061
http://dx.doi.org/10.3390/molecules26102998
Descripción
Sumario:The reaction of the redox active 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dpp-BIAN) and iron(II) iodide in acetonitrile led to a new complex [(dpp-BIAN)Fe(II)I(2)] (1). Molecular structure of 1 was determined by the single crystal X-ray diffraction analysis. The spin state of the iron cation in complex 1 at room temperature and the magnetic behavior of 1 in the temperature range of 2–300 K were studied using Mossbauer spectroscopy and magnetic susceptibility measurements, respectively. The neutral character of dpp-BIAN in 1 was confirmed by IR and UV spectroscopy. The electrochemistry of 1 was studied in solution and solid state using cyclic voltammetry. The generation of the radical anion form of the dpp-BIAN ligand upon reduction of 1 in a CH(2)Cl(2) solution was monitored by EPR spectroscopy.

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