Rationalizing the diverse reactivity of [1.1.1]propellane through σ–π-delocalization

[1.1.1]Propellane is the ubiquitous precursor to bicyclo[1.1.1]pentanes (BCPs), motifs of high value in pharmaceutical and materials research. The classical Lewis representation of this molecule places an inter-bridgehead C–C bond along its central axis; ‘strain relief’-driven cleavage of this bond...

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Detalles Bibliográficos
Autores principales: Sterling, Alistair J., Dürr, Alexander B., Smith, Russell C., Anderson, Edward A., Duarte, Fernanda
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159217/
https://www.ncbi.nlm.nih.gov/pubmed/34122945
http://dx.doi.org/10.1039/d0sc01386b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159217/
https://www.ncbi.nlm.nih.gov/pubmed/34122945
http://dx.doi.org/10.1039/d0sc01386b

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