Nitric oxide monooxygenation (NOM) reaction of cobalt-nitrosyl {Co(NO)}(8) to Co(II)-nitrito {Co(II)(NO(2)(−))}: base induced hydrogen gas (H(2)) evolution

Here, we report the nitric oxide monooxygenation (NOM) reactions of a Co(III)-nitrosyl complex (1, {Co-NO}(8)) in the presence of mono-oxygen reactive species, i.e., a base (OH(−), tetrabutylammonium hydroxide (TBAOH) or NaOH/15-crown-5), an oxide (O(2−) or Na(2)O/15-crown-5) and water (H(2)O). The...

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Detalles Bibliográficos
Autores principales: Das, Sandip, Kulbir, Ghosh, Somnath, Chandra Sahoo, Subash, Kumar, Pankaj
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159239/
https://www.ncbi.nlm.nih.gov/pubmed/34122960
http://dx.doi.org/10.1039/d0sc01572e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159239/
https://www.ncbi.nlm.nih.gov/pubmed/34122960
http://dx.doi.org/10.1039/d0sc01572e

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