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An iron ketimide single-molecule magnet [Fe(4)(N[double bond, length as m-dash]CPh(2))(6)] with suppressed through-barrier relaxation
Reaction of FeBr(2) with 1.5 equiv. of LiN[double bond, length as m-dash]CPh(2) and 2 equiv. of Zn, in THF, results in the formation of the tetrametallic iron ketimide cluster [Fe(4)(N[double bond, length as m-dash]CPh(2))(6)] (1) in moderate yield. Formally, two Fe centers in 1 are Fe(i) and two ar...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159258/ https://www.ncbi.nlm.nih.gov/pubmed/34122931 http://dx.doi.org/10.1039/d0sc01578d |