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Rapidly self-deoxygenating controlled radical polymerization in water via in situ disproportionation of Cu(i)
Rapidly self-deoxygenating Cu-RDRP in aqueous media is investigated. The disproportionation of Cu(i)/Me(6)Tren in water towards Cu(ii) and highly reactive Cu(0) leads to O(2)-free reaction environments within the first seconds of the reaction, even when the reaction takes place in the open-air. By l...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159280/ https://www.ncbi.nlm.nih.gov/pubmed/34122982 http://dx.doi.org/10.1039/d0sc01512a |