Carboxylate breaks the arene C–H bond via a hydrogen-atom-transfer mechanism in electrochemical cobalt catalysis

Combined computational and experimental studies elucidated the distinctive mechanistic features of electrochemical cobalt-catalyzed C–H oxygenation. A sequential electrochemical–chemical (EC) process was identified for the formation of an amidylcobalt(iii) intermediate. The synthesis, characterizati...

Descripción completa

Detalles Bibliográficos
Autores principales: Chen, Xin-Ran, Zhang, Shuo-Qing, Meyer, Tjark H., Yang, Chun-Hui, Zhang, Qin-Hao, Liu, Ji-Ren, Xu, Hua-Jian, Cao, Fa-He, Ackermann, Lutz, Hong, Xin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159317/
https://www.ncbi.nlm.nih.gov/pubmed/34094081
http://dx.doi.org/10.1039/d0sc01898h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159317/
https://www.ncbi.nlm.nih.gov/pubmed/34094081
http://dx.doi.org/10.1039/d0sc01898h

Ejemplares similares