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Carboxylate breaks the arene C–H bond via a hydrogen-atom-transfer mechanism in electrochemical cobalt catalysis
Combined computational and experimental studies elucidated the distinctive mechanistic features of electrochemical cobalt-catalyzed C–H oxygenation. A sequential electrochemical–chemical (EC) process was identified for the formation of an amidylcobalt(iii) intermediate. The synthesis, characterizati...
Autores principales: | Chen, Xin-Ran, Zhang, Shuo-Qing, Meyer, Tjark H., Yang, Chun-Hui, Zhang, Qin-Hao, Liu, Ji-Ren, Xu, Hua-Jian, Cao, Fa-He, Ackermann, Lutz, Hong, Xin |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159317/ https://www.ncbi.nlm.nih.gov/pubmed/34094081 http://dx.doi.org/10.1039/d0sc01898h |
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