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Stereo-controlled anti-hydromagnesiation of aryl alkynes by magnesium hydrides

A concise protocol for anti-hydromagnesiation of aryl alkynes was established using 1 : 1 molar combination of sodium hydride (NaH) and magnesium iodide (MgI(2)) without the aid of any transition metal catalysts. The resulting alkenylmagnesium intermediates could be trapped with a series of electrop...

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Detalles Bibliográficos
Autores principales:	Wang, Bin, Ong, Derek Yiren, Li, Yihang, Pang, Jia Hao, Watanabe, Kohei, Takita, Ryo, Chiba, Shunsuke
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159320/ https://www.ncbi.nlm.nih.gov/pubmed/34122983 http://dx.doi.org/10.1039/d0sc01773f

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