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BNN-1,3-dipoles: isolation and intramolecular cycloaddition with unactivated arenes

The mono-base-stabilized 1,2-diboranylidenehydrazine derivatives featuring a 1,3-dipolar BNN skeleton are obtained by dehydrobromination of [ArB(Br)NH](2) (Ar = 2,6-diphenylphenyl (Dpp), Ar = 2,6-bis(2,4,6-trimethylphenyl)phenyl (Dmp) or Ar = 2,4,6-tri-tert-butylphenyl (Mes*)) with N-heterocyclic ca...

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Detalles Bibliográficos
Autores principales: Guo, Rui, Jiang, Jingxing, Hu, Chenyang, Liu, Liu Leo, Cui, Ping, Zhao, Meihua, Ke, Zhuofeng, Tung, Chen-Ho, Kong, Lingbing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159347/
https://www.ncbi.nlm.nih.gov/pubmed/34122998
http://dx.doi.org/10.1039/d0sc02162h

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