Cargando…

Photo-induced carbocation-enhanced charge transport in single-molecule junctions

We report the first example of photo-induced carbocation-enhanced charge transport in triphenylmethane junctions using the scanning tunneling microscopy break junction (STM-BJ) technique. The electrical conductance of the carbocation state is enhanced by up to 1.5 orders of magnitude compared to the...

Descripción completa

Detalles Bibliográficos
Autores principales:	Bei, Zhongwu, Huang, Yuan, Chen, Yangwei, Cao, Yiping, Li, Jin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2020
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159380/ https://www.ncbi.nlm.nih.gov/pubmed/34094094 http://dx.doi.org/10.1039/d0sc00505c

Ejemplares similares

Charge transport through single-molecule bilayer-graphene junctions with atomic thickness
por: Zhao, Shiqiang, et al.
Publicado: (2022)

OH radical-initiated single-electron transfer for accelerated degradation via carbocation intermediates
por: Ge, Xiyang, et al.
Publicado: (2023)

Hyperconjugation in Carbocations, a BLW Study with DFT approximation
por: Alamiddine, Zakaria, et al.
Publicado: (2014)

Molecular Orbital Insights of Transition Metal-Stabilized Carbocations
por: Goodman, Hannah, et al.
Publicado: (2019)

Pushing the limits of concertedness. A waltz of wandering carbocations
por: Castiñeira Reis, Marta, et al.
Publicado: (2018)

Charge transport in a zinc–porphyrin single-molecule junction
por: Perrin, Mickael L, et al.
Publicado: (2011)

Recent developments in carbocation and onium ion chemistry
por: Laali, Kenneth K
Publicado: (2007)

Fast detection and structural identification of carbocations on zeolites by dynamic nuclear polarization enhanced solid-state NMR
por: Xiao, Dong, et al.
Publicado: (2018)

Anomalous effect of non-alternant hydrocarbons on carbocation and carbanion electronic configurations
por: Fischer, Logan J., et al.
Publicado: (2017)

Spontaneous Transition of Alkyl Carbocations to Unsaturated Vinyl-Type Carbocations in Organic Solutions
por: Stoyanov, Evgenii S., et al.
Publicado: (2023)

Mechanistically informed predictions of binding modes for carbocation intermediates of a sesquiterpene synthase reaction
por: O'Brien, T. E., et al.
Publicado: (2016)

Carbocation catalysis in confined space: activation of trityl chloride inside the hexameric resorcinarene capsule
por: De Rosa, Margherita, et al.
Publicado: (2022)

Understanding resonant charge transport through weakly coupled single-molecule junctions
por: Thomas, James O., et al.
Publicado: (2019)

Reflex Carbocation Release from Covalent Molecules by Endogenous Free Radicals
por: Walton, John C.
Publicado: (2018)

Ultrafast C–C and C–N bond formation reactions in water microdroplets facilitated by the spontaneous generation of carbocations
por: Wang, Ting, et al.
Publicado: (2023)

Annulation cascade of arylnitriles with alkynes to stable delocalized PAH carbocations via intramolecular rhodium migration
por: Yin, Jiangliang, et al.
Publicado: (2018)

Caryolene-forming carbocation rearrangements
por: Nguyen, Quynh Nhu N, et al.
Publicado: (2013)

Can a gas phase contact ion pair containing a hydrocarbon carbocation be formed in the ground state?
por: Araújo, José R., et al.
Publicado: (2021)

The cyclopropylcarbinyl route to γ-silyl carbocations
por: Creary, Xavier
Publicado: (2019)

Single-molecule junctions of multinuclear organometallic wires: long-range carrier transport brought about by metal–metal interaction
por: Tanaka, Yuya, et al.
Publicado: (2021)

Electronic transport through single-molecule oligophenyl-diethynyl junctions with direct gold–carbon bonds formed at low temperature
por: Mitra, Gautam, et al.
Publicado: (2021)

Charge transport in liquid crystal network of terthiophene-siloxane block molecules
por: Sakaino, Hirotoshi, et al.
Publicado: (2022)

Single-molecule detection of dihydroazulene photo-thermal reaction using break junction technique
por: Huang, Cancan, et al.
Publicado: (2017)

Engineering Transport Orbitals in Single-Molecule Junctions
por: Daaoub, Abdalghani, et al.
Publicado: (2022)

Protonation tuning of quantum interference in azulene-type single-molecule junctions
por: Yang, Guogang, et al.
Publicado: (2017)

Single-molecule dynamic DNA junctions for engineering robust molecular switches
por: Cai, Shuang, et al.
Publicado: (2019)

Mechanical conductance tunability of a porphyrin–cyclophane single-molecule junction
por: Schosser, Werner M., et al.
Publicado: (2021)

Origin and mechanism analysis of asymmetric current fluctuations in single-molecule junctions
por: Gu, Chunhui, et al.
Publicado: (2018)

Hydrogen-bond-induced quantum interference in single-molecule junctions of regioisomers
por: Ge, Lingbing, et al.
Publicado: (2022)

Dynamic Induction of Optical Activity in Triarylmethanols and Their Carbocations
por: Stasiak, Bartosz, et al.
Publicado: (2020)

Conjugative Stabilization versus Anchimeric Assistance in Carbocations
por: Shainyan, Bagrat A.
Publicado: (2022)

Sensing force and charge at the nanoscale with a single-molecule tether
por: Meng, Xuanhui, et al.
Publicado: (2021)

Exploring room-temperature transport of single-molecule magnet-based molecular spintronics devices using the magnetic tunnel junction as a device platform
por: Tyagi, Pawan, et al.
Publicado: (2020)

Photo-induced imino functionalizations of alkenes via intermolecular charge transfer
por: Zhang, Xiang-Xin, et al.
Publicado: (2023)

Enhancement of charge transport properties of small molecule semiconductors by controlling fluorine substitution and effects on photovoltaic properties of organic solar cells and perovskite solar cells
por: Yun, Jae Hoon, et al.
Publicado: (2016)

Anti-ohmic single molecule electron transport: is it feasible?
por: Gil-Guerrero, Sara, et al.
Publicado: (2019)

Dynamic behavior of rearranging carbocations – implications for terpene biosynthesis
por: Hare, Stephanie R, et al.
Publicado: (2016)

Molecular Determinants of Carbocation Cyclisation in Bacterial Monoterpene Synthases
por: Leferink, Nicole G. H., et al.
Publicado: (2022)

Electrical and SERS detection of disulfide-mediated dimerization in single-molecule benzene-1,4-dithiol junctions
por: Zheng, Jueting, et al.
Publicado: (2018)

Novel class of photochromic molecules exhibiting photo-switching in the solid state
por: Loan, Thomas, et al.
Publicado: (2023)

Cannot write session to /tmp/vufind_sessions/sess_t8cfre7bhrc6f2uf6m0mk0fkjl