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Speciation of Be(2+) in acidic liquid ammonia and formation of tetra- and octanuclear beryllium amido clusters
The hexa-μ(2)-amido-tetraammine-tetraberyllium compounds [Be(4)(NH(2))(6)(NH(3))(4)]X(2) (X = Cl, Br, I, CN, SCN, N(3)) have been prepared from beryllium metal and NH(4)X or [Be(NH(3))(4)]X(2) in liquid ammonia at ambient temperature. The obtained compounds feature an adamantyl shaped complex cation...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159412/ https://www.ncbi.nlm.nih.gov/pubmed/34094068 http://dx.doi.org/10.1039/d0sc01112f |