Ortho C–H arylation of arenes at room temperature using visible light ruthenium C–H activation

A ruthenium-catalyzed ortho C–H arylation process is described using visible light. Using the readily available catalyst [RuCl(2)(p-cymene)](2), visible light irradiation was found to enable arylation of 2-aryl-pyridines at room temperature for a range of aryl bromides and iodides.

Detalles Bibliográficos
Autores principales: Sagadevan, Arunachalam, Charitou, Anastasios, Wang, Fen, Ivanova, Maria, Vuagnat, Martin, Greaney, Michael F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159458/
https://www.ncbi.nlm.nih.gov/pubmed/34122900
http://dx.doi.org/10.1039/d0sc01289k
Descripción
Sumario:A ruthenium-catalyzed ortho C–H arylation process is described using visible light. Using the readily available catalyst [RuCl(2)(p-cymene)](2), visible light irradiation was found to enable arylation of 2-aryl-pyridines at room temperature for a range of aryl bromides and iodides.

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