Ortho C–H arylation of arenes at room temperature using visible light ruthenium C–H activation

A ruthenium-catalyzed ortho C–H arylation process is described using visible light. Using the readily available catalyst [RuCl(2)(p-cymene)](2), visible light irradiation was found to enable arylation of 2-aryl-pyridines at room temperature for a range of aryl bromides and iodides.

Detalles Bibliográficos
Autores principales: Sagadevan, Arunachalam, Charitou, Anastasios, Wang, Fen, Ivanova, Maria, Vuagnat, Martin, Greaney, Michael F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159458/
https://www.ncbi.nlm.nih.gov/pubmed/34122900
http://dx.doi.org/10.1039/d0sc01289k
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author Sagadevan, Arunachalam
Charitou, Anastasios
Wang, Fen
Ivanova, Maria
Vuagnat, Martin
Greaney, Michael F.
author_facet Sagadevan, Arunachalam
Charitou, Anastasios
Wang, Fen
Ivanova, Maria
Vuagnat, Martin
Greaney, Michael F.
author_sort Sagadevan, Arunachalam
collection PubMed
description A ruthenium-catalyzed ortho C–H arylation process is described using visible light. Using the readily available catalyst [RuCl(2)(p-cymene)](2), visible light irradiation was found to enable arylation of 2-aryl-pyridines at room temperature for a range of aryl bromides and iodides.
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spelling pubmed-81594582021-06-11 Ortho C–H arylation of arenes at room temperature using visible light ruthenium C–H activation Sagadevan, Arunachalam Charitou, Anastasios Wang, Fen Ivanova, Maria Vuagnat, Martin Greaney, Michael F. Chem Sci Chemistry A ruthenium-catalyzed ortho C–H arylation process is described using visible light. Using the readily available catalyst [RuCl(2)(p-cymene)](2), visible light irradiation was found to enable arylation of 2-aryl-pyridines at room temperature for a range of aryl bromides and iodides. The Royal Society of Chemistry 2020-04-07 /pmc/articles/PMC8159458/ /pubmed/34122900 http://dx.doi.org/10.1039/d0sc01289k Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Sagadevan, Arunachalam
Charitou, Anastasios
Wang, Fen
Ivanova, Maria
Vuagnat, Martin
Greaney, Michael F.
Ortho C–H arylation of arenes at room temperature using visible light ruthenium C–H activation
title Ortho C–H arylation of arenes at room temperature using visible light ruthenium C–H activation
title_full Ortho C–H arylation of arenes at room temperature using visible light ruthenium C–H activation
title_fullStr Ortho C–H arylation of arenes at room temperature using visible light ruthenium C–H activation
title_full_unstemmed Ortho C–H arylation of arenes at room temperature using visible light ruthenium C–H activation
title_short Ortho C–H arylation of arenes at room temperature using visible light ruthenium C–H activation
title_sort ortho c–h arylation of arenes at room temperature using visible light ruthenium c–h activation
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159458/
https://www.ncbi.nlm.nih.gov/pubmed/34122900
http://dx.doi.org/10.1039/d0sc01289k
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