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Redox deracemization of β,γ-alkynyl α-amino esters

The first non-enzymatic redox deracemization method using molecular oxygen as the terminal oxidant has been described. The one-pot deracemization of β,γ-alkynyl α-amino esters consisted of a copper-catalyzed aerobic oxidation and chiral phosphoric acid-catalyzed asymmetric transfer hydrogenation wit...

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Detalles Bibliográficos
Autores principales: Zhang, Lu, Zhu, Rongxiu, Feng, Aili, Zhao, Changyin, Chen, Lei, Feng, Guidong, Liu, Lei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8159540/
https://www.ncbi.nlm.nih.gov/pubmed/34122901
http://dx.doi.org/10.1039/d0sc00944j

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