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Total synthesis of endiandric acid J and beilcyclone A from cyclooctatetraene

The endiandric acids are classic targets in natural product synthesis. The spectacular 8π/6π-electrocylisation/intramolecular Diels–Alder (8π/6π/IMDA) reaction cascade at the heart of their biosynthesis has inspired practitioners and students of pericyclic chemistry for nearly forty years. All previ...

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Detalles Bibliográficos
Autores principales: Yahiaoui, Oussama, Almass, Adrian, Fallon, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8161681/
https://www.ncbi.nlm.nih.gov/pubmed/34094208
http://dx.doi.org/10.1039/d0sc03073b