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Synthetic studies toward longeracemine: a SmI(2)-mediated spirocyclization and rearrangement cascade to construct the 2-azabicyclo[2.2.1]heptane framework
Longeracemine, a member of the Daphniphyllum family of alkaloids contains a novel carbon framework featuring a highly functionalized 2-azabicyclo[2.2.1]heptane core as part of an overall 5/6/5/5/6/5 skeleton. A synthetic intermediate containing the core of longeracemine has been efficiently prepared...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162136/ https://www.ncbi.nlm.nih.gov/pubmed/34094215 http://dx.doi.org/10.1039/d0sc03422c |