Extension of the Simmons–Smith reaction to metal-carbynes: efficient synthesis of metallacyclopropenes with σ-aromaticity

The Simmons–Smith reaction offers a direct route for conversion of an alkene into a cyclopropane with a zinc carbenoid as the active intermediate. Zinc carbenoids, however, have never delivered a methylene unit to substrates with metal–carbon multiple bonds. Herein, we describe this type of reaction...

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Detalles Bibliográficos
Autores principales: Huang, Fanping, Zheng, Xuejuan, Lin, Xinlei, Ding, Linting, Zhuo, Qingde, Wen, Ting Bin, Zhang, Hong, Xia, Haiping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162146/
https://www.ncbi.nlm.nih.gov/pubmed/34094279
http://dx.doi.org/10.1039/d0sc03215h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162146/
https://www.ncbi.nlm.nih.gov/pubmed/34094279
http://dx.doi.org/10.1039/d0sc03215h

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