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Using light intensity to control reaction kinetics and reversibility in photomechanical crystals

4-Fluoro-9-anthracenecarboxylic acid (4F-9AC) is a thermally reversible (T-type) photomechanical molecular crystal. The photomechanical response is driven by a [4 + 4] photodimerization reaction, while the photodimer dissociation determines the reset time. In this paper, both the chemical kinetics o...

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Detalles Bibliográficos
Autores principales: Easley, Connor J., Tong, Fei, Dong, Xinning, Al-Kaysi, Rabih O., Bardeen, Christopher J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162182/
https://www.ncbi.nlm.nih.gov/pubmed/34094245
http://dx.doi.org/10.1039/d0sc03557b